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Document Details
Document Type
:
Article In Journal
Document Title
:
Calalytic activity of K10-montmorillonite in reaction of arenes with some mono- and di-functional al
Calalytic activity of K10-montmorillonite in reaction of arenes with some mono- and di-functional al
Document Language
:
Arabic
Abstract
:
K10-montmorillonite has been tested as Friedel-Crafts catalyst in the alkylation of benzene, toluene and anisole with one or more of the alkylating agents 1-10. The reaction products consisted essentially of 1,1- and 1,2-diaryl-2-methylpropane derivatives (e.g. 11 and 12 respectively) together with side products resulting from transalkylation, monoalkylation. hvdride transfer and elimination. K 10-montmorillonite has also been used to catalyse the alkylation of naphthalene with benzyl alcohol whereby a mixture of alpha- and beta-benzylnaphthalene Is obtained. The results, explained in terms of carbocation transformations, show K 10-montmorillonite to be a mild catalyst with no subsequent side-chain Isomerising ability just like FeCl3, AlCl3-CH3NO2, TiCl4 and ZrCl4.
Journal Name
:
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY
Volume
:
35
Issue Number
:
1
Publishing Year
:
1996 AH
Added Date
:
Saturday, June 14, 2008
Researchers
Researcher Name (Arabic)
Researcher Name (English)
Researcher Type
Dr Grade
Email
سالم أحمد باسيف
Researcher
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